Cyclization of Oxindolic methylketones with acid : A rapid synthesis of (±)-aspidofractinine
Identifieur interne : 001262 ( Main/Exploration ); précédent : 001261; suivant : 001263Cyclization of Oxindolic methylketones with acid : A rapid synthesis of (±)-aspidofractinine
Auteurs : Dominique Cartier [France] ; Mohammed Ouahrani [France] ; Jean Lévy [France]Source :
- Tetrahedron Letters [ 0040-4039 ] ; 1989.
Abstract
The oxindolic methylketone 7 was cyclized in one step to the hexacyclic ketolactam 9 with acid. (±)-Aspidofractinine 23 was prepared by sequential reduction of 9. The model oxindolic methylketone 11, when reacted with acid, gave compounds 12 and 17a,b.
Url:
DOI: 10.1016/S0040-4039(00)99622-9
Affiliations:
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<front><div type="abstract" xml:lang="en">The oxindolic methylketone 7 was cyclized in one step to the hexacyclic ketolactam 9 with acid. (±)-Aspidofractinine 23 was prepared by sequential reduction of 9. The model oxindolic methylketone 11, when reacted with acid, gave compounds 12 and 17a,b.</div>
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